Ed., 2005, 44: 6362-6366 Cho S H, Ma B, Nguyen S T, Hupp J T, Albrecht-Schmitt T E. Catal., 2010, 270: 26-33 Lu Y, Tonigold M, Bredenkötter B, Volkmer D, Hitzbleck J, Langstein G. Catal., 2008, 255: 220-227 Jiang D, Mallat T, Meier D M, Urakawa A, Baiker A. Catal., 2009, 267: 1-4 Llabrés I, Xamena F X, Casanova O, Tailleur R G, Garcia H, Corma A. Microporous and Mesoporous Mater., 2004, 73(1/2): 81-88 Horike S, Dinca M, Tamaki K, Long J R. Science, 2008, 319 (5865): 939-943 Meilikhov M, Yusenko K, Esken D, Turner S, van Tendeloo G, Fischer R A. Rev., 2009, 38: 1315-1329 Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O’Keeffe M, Yaghi O M. Commun., 2002, 2872-2873 Hwang Y K, Hong D Y, Chang J S, Seo H, Yoon M, Kim J, Jhung S H, Serre C, Férey G. Mater., 2005, 17(11): 2866-2874 Chen B L, Ockwig N W, Fronczek F R, Contreras D S, Yaghi O M. Soc., 2011, 133: 13445-13454 Chen X Y, Zhao B, Shi W, Xia J, Cheng P, Liao D Z, Yan S P, Jiang Z H. Soc., 2002, 124: 15326-15335 Chui S S Y, Lo S M F, Charmant J P H, Orpen A G, Williams I D. Ed., 2004, 43: 6296-6301 Férey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Surblé S, Margiolaki I. PNAS, 2006, 103: 10186-10191 Férey G, Serre C, Mellot-Draznieks C, Millange F, Surblé S, Dutour J, Margiolaki I. Science, 2002, 295: 469-472 Park K S, Ni Z, Cote A P, Choi J Y, Huang R, Uribe-Romo F J, Chae H K, O’Keeffe M, Yaghi O M. Nature, 1999, 402: 276-279 Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi O M. 北京化工大学博士论文 (Doctoral Dissertation of Beijing University of Chemical Technology), 2010 Ma S, Zhou H C. 吉林大学博士论文 (Doctoral Dissertation of Jilin University), 2010 许青 (Xu Q).

Phys., 2011, 13: 6388-6396 Furukawa H, Ko N, Go Y B, Aratani N, Choi S B, Choi E, Yazaydin A O, Snurr R Q, O’Keeffe M, Kim J, Yaghi O M. Res., 2011, 50: 1799-1812 Allendorf M D, Bauer C A, Bhaktaa R K, Houk R J T. The development trends of MOF materials in the catalytic applications are also prospected.Ģ Categories and syntheses of MOFs materialsģ.1 Catalytic reactions of MOFs with metal active sitesģ.2 Catalytic reactions of MOFs with active organic ligandsģ.3 Catalytic reactions of MOFs with loading active guests

The catalysis of the MOF materials, especially, the catalysis of the metal active sites and the active organic ligands in the frameworks of the MOF, and the catalytic active components supported in MOFs, are summarized and reviewed. In order to get comprehensive understanding of the MOFs’ catalytic properties, in this paper, the categories and common synthesis methods of MOF materials are introduced. Because of their diverse structures, tunable cavity and easy functionalization, MOFs have exhibited the attractive prospects in many fields, such as the gas adsorption and separation, the catalysts, the magnetism and the bio-medicine. Metal-organic Framework (MOF) materials, which are synthesized by self-assembling of the metal ions and the organic ligands, are the special crystal materials with porous structure.

Fx chem 2.006